Molecular self-diffusion in micellar and discrete cubic phases of an ionic surfactant with mixed monovalent/polymeric counterions
The molecular self-diffusion in concentrated aqueous mixtures based on an oppositely charged po ymer-surfactant pair has been investigated by NMR pulsed field gradient techniques. The investigated structures were an ordered cubic Pm3n phase (ca. 50 wt % water) and a disordered micellar phase, both containing cetyltrimethylammonium (CTA(+)) micelles with mixed acetate (Ac-) and polyacrylate (PA(-))