Kinetics and mechanisms in the ammoxidation of toluene over a V2O5 catalyst. Part 2: Non-selective reactions
In the ammoxidation of toluene over a V2O5 catalyst, the variation of initial rates with partial pressures of oxygen, toluene and ammonia was determined for formation of carbon oxides. Dependencies obtained were analyzed and expressed in terms of rate equations. It was found that CO and CO2 are initial products formed at different sites, none of which are involved in selective reactions. The mecha