Improved arsenic(III) adsorption by Al2O3 nanoparticles and H2O2: Evidence of oxidation to arsenic(V) from X-ray absorption spectroscopy.
We have investigated the oxidation of inorganic As(III) with H2O2 catalysed by Al2O3, using X-ray absorption near-edge structure and extended X-ray absorption fine structure spectroscopy. The effects of different reaction conditions (pH, time and initial H2O2 concentration) were also studied as were the kinetics of the oxidation reaction. We demonstrated that As(III) was oxidized to As(V) in the p
