Aliphatic β-Blocked Ligands in POCOP Pincer Complex Synthesis
Introduction: Synthesis of novel aliphatic POCOP pincer complexes with β-blocking alkyl groups. Background: An issue with Aliphatic POCOP pincer complexes is that the sought-after C=M bond is unstable with previous attempts forming aromatic groups or decomposing completely under heating. By introducing β-blocking elements to the aliphatic POCOP pincer ligands could this mitigate the decompositio