Triiron and triruthenium carbonyl clusters bearing bridging long chain diphosphine and capping chalcogenido ligands
Treatment of Ru-3(CO)(12) with dpphSe(2) (dpph = 1,6-bis(diphenylphosphino)-hexane) in refluxing toluene in the presence of Me3NO afforded two new compounds, Ru-3(CO)(7)(mu-CO)(mu(3)-Se)(mu-dpph) (1) and Ru-3(CO)(7)(mu(3)-Se)(2)(mu-dpph) (2). A similar reaction of Ru-3(CO)(12) with dpppeSe(2)(dpppe=1,5-bis(diphenylphosphino)pentane) gave exclusively Ru-3(CO)(7)(mu(3)-Se)(2)(mu-dpppe) (3). Treatmen