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Kinetics and Mechanism for Reduction of trans-Dichlorotetracyanoplatinate(IV) by Thioglycolic Acid, L-Cysteine, D,L-Penicillamine, and Glutathione in Aqueous Solution

SynopsisVarious protolytic species of thiols RSH (thioglycolic acid, l-cysteine, dl-penicillamine, and glutathione) in rapid equilibria with each other reduce trans-[Pt(CN)4Cl2]2- in parallel, halide-bridged electron transfer reactions. A linear Brønsted correlation between the reactivity of the thiolate anions RS- and their basicity is observed. The mechanism derived might be used as a model for

Drivers and Barriers for a Sustainable Energy Solution

RESEARCH QUESTION: What are the main drivers and barriers affecting the Swedish energy industry and its institutional logic? PURPOSE: The purpose of this study is to examine the drivers and barriers affecting the Swedish energy sector and its institutional logic. THEORETICAL PERSPECTIVE:The theories used for this paper, give the reader an overview of the subject and include: Dominant Logic, Invest