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Ultrafast two-electron transfer drives 2MLCT to 2LMCT excited state conversion in a novel iron(III) dual charge transfer absorber complex

The development of sustainable photosensitiser complexes based on Earth-abundant metallic elements is important for sustainable solar energy conversion and green synthesis through photocatalysis. We report the synthesis and characterisation of a new bis(tripodal) iron(III) N-heterocyclic carbene complex [Fe(PhB{impy}3)2]+ (PhB{impy}3 = phenyltris(imidazo-[1,5-a]-pyridinylidene)borate) featuring -e

Photoinduced Hydrogen Evolution Catalyzed by Co(II) Complexes of N5-Donor Ligands

Three new cobalt complexes of the general formula [Co(II)(L)(CH3CN)]2+, where L is one of three pentadentate nitrogen-donor ligands based on the N4Py framework, have been synthesized and characterized. The capacity of the three complexes to effect photocatalytic proton reduction has been examined. Their photocatalytic activities in the presence of [Ru(bpy)3]2+, acting as a photosensitizer, and asc

Echocardiographic right ventricular strain from multiple apical views is superior for assessment of right ventricular systolic function

Background: Right ventricular (RV) systolic function is an important determinant of outcome in patients with pulmonary hypertension (PH). Conventional echocardiographic measures of RV are mainly based on longitudinal contractility. Recently, measurement of RV global longitudinal strain derived from multiple windows (RVGLS) has emerged as an option but has not been well evaluated. The aim of the pr

Monitoring Data for Anomaly Detection in Cloud-Based Systems : A Systematic Mapping Study

Context: Anomaly detection is crucial for maintaining cloud-based software systems, as it enables early identification and resolution of unexpected failures. Given rapid and significant advances in the anomaly detection domain and the complexity of its industrial implementation, an overview of techniques that utilize real-world operational data is needed. Aim: This study aims to complement existin

Validation of SenseWear Armband in children, adolescents, and adults

SenseWear Armband (SW) is a multisensor monitor to assess physical activity and energy expenditure. Its prediction algorithms have been updated periodically. The aim was to validate SW in children, adolescents, and adults. The most recent SW algorithm 5.2 (SW5.2) and the previous version 2.2 (SW2.2) were evaluated for estimation of energy expenditure during semi-structured activities in 35 childre

Captivating bimolecular photoredox dynamics of a ligand-to-metal charge transfer complex

Transition metal complexes featuring ligand-to-metal charge transfer (LMCT) excited states have been identified as promising candidates for driving electron transfer processes. To obtain an efficient system based on photo-induced bimolecular electron transfer, it is required that (1) photo-induced charge separation (CS) is faster than charge recombination (CR) of the separated charges, and (2) CR

Comorbidities and mortality in subgroups of adults with diabetes with up to 14 years follow-up : a prospective cohort study in Sweden

Background: Subgroups of adult-onset diabetes, namely severe autoimmune diabetes (SAID), severe insulin-deficient diabetes (SIDD), severe insulin-resistant diabetes (SIRD), and mild obesity-related diabetes (MOD) or mild age-related (MARD) diabetes, have been defined with clinical variables and a machine-learning approach. Our aim was to describe their long-term outcomes and mortality. Methods: In

EEG glasses for real-time brain electrical activity monitoring

Wearable devices are becoming a cornerstone for personalized and long-term health monitoring, enabling early intervention and data-driven medical decisions. In this work, we present e-Glass, a state-of-the-art smart wearable device that enables unobtrusive real-time electroencephalography (EEG) monitoring. Our evaluation shows that e-Glass adheres to the established international guidelines for cl

G utbildningen - kursplaner ak 3-5 termin 5-9

Microsoft Word - 1011_kursplan_G_termin5-9.doc Lunds Universitet Musikhögskolan i Malmö, Box 8203, 200 41 Malmö, 040-32 54 50 www.mhm.lu.se           Kursplaner G utbildningen 2010/2011 åk 3-5 termin 5-9 Lunds Universitet Musikhögskolan i Malmö Musiklärarutbildningen Utbildningsöversikt Huvudämne Gemensam Del Sidoämne Kursplaner för G utbildningen, åk 3-5, termin 5-9 Lunds Universitet 2010/2011 Mu

https://www.mhm.lu.se/sites/mhm.lu.se/files/g_utbildningen_-_kursplaner_ak_3-5_termin_5-9_.pdf - 2026-05-30

Advancing 90-day mortality and anastomotic leakage predictions after oesophagectomy for cancer using Explainable Artificial Intelligence

Introduction: Oesophageal resection carries significant morbidity and mortality. Artificial intelligence (AI) advances in medical research enable enhanced predictions, flexibility, and interpretability, especially for complex interactions and nonlinear relationships. Material and methods: We used a register-based case-control design nested within prospectively collected data from the Swedish Natio

Large Eddy Simulation of Thermo-Acoustic Instabilities in Bluff-Body Stabilized Flames; A Comparison Between Jet-A and C1

Due to the threat climate change poses, the aviation industry needs to adapt. In the process to convert the aviation fleet into a more environmentally friendly fleet, using biofuels such as Sustainable Aviation Fuels as a drop-in fuel remains a promising option. To include biofuels, safety aspects need to be investigated, where combustion instabilities are important. Thermo-acoustic instabilities

LES of Stable Combustion and Lean Blow-out in a Mach 2 Cavity Flameeholder

This study presents high-fidelity Large Eddy Simulations (LES) of supersonic combustion in a Mach 2 cavity flameholder over the full stable fueling region from 40 to 200 slpm. The simulations employ Finite Rate Chemistry LES with the Z70 ethylene-air mechanism, the Localized Dynamic k-equation model, Partially Stirred Reactor turbulence-chemistry interaction model, conjugate heat transfer, and the

Resolving consecutive excited-state evolution in Fe-amido chromophores by wide-band optical transient absorption spectroscopy

A detailed understanding of excited-state evolution is critical to realizing the full potential of abundant-metal coordination complex photosensitizers. Here, we show how wide-band optical transient absorption spectroscopy (oTA) can delineate the complete energy relaxation pathway of the photoexcited state of Fe(ii) polypyridyl complexes supported by benzannulated diarylamido ligands. By covering

Defining the Minimal Factors Required for Erythropoiesis through Direct Lineage Conversion

Erythroid cell commitment and differentiation proceed through activation of a lineage-restricted transcriptional network orchestrated by a group of well characterized genes. However, the minimal set of factors necessary for instructing red blood cell (RBC) development remains undefined. We employed a screen for transcription factors allowing direct lineage reprograming from fibroblasts to induced

Nature of Self-Trapped Exciton Emission in Zero-Dimensional Cs2ZrCl6 Perovskite Nanocrystals

Low dimensional perovskite-inspired materials with self-tapped exciton (STE) emission have stimulated a surge of cutting-edge research in optoelectronics. Despite numerous efforts on developing versatile low-dimensional perovskite-inspired materials with efficient STE emissions, there is little emphasis on the intrinsic dynamics of STE-based broad emission in these materials. Here, we investigated

The 5-Hydroxymethylcytosine Landscape of Prostate Cancer

Analysis of DNA methylation is a valuable tool to understand disease progression and is increasingly being used to create diagnostic and prognostic clinical biomarkers. While conversion of cytosine to 5-methylcytosine (5mC) commonly results in transcriptional repression, further conversion to 5-hydroxymethylcytosine (5hmC) is associated with transcriptional activation. Here we perform the first st