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Manipulating crystallization dynamics through chelating molecules for bright perovskite emitters

Molecular additives are widely utilized to minimize non-radiative recombination in metal halide perovskite emitters due to their passivation effects from chemical bonds with ionic defects. However, a general and puzzling observation that can hardly be rationalized by passivation alone is that most of the molecular additives enabling high-efficiency perovskite light-emitting diodes (PeLEDs) are che

Electronic Structure and Trap States of Two-Dimensional Ruddlesden–Popper Perovskites with the Relaxed Goldschmidt Tolerance Factor

Two-dimensional Ruddlesden–Popper perovskites (2D RPPs) have been considered as promising building blocks for optoelectronic applications owing to optical properties comparable to the ones of 3D perovskites, together with superior stability. In addition, the more flexible structure adopted by such perovskites leads to a relaxation of the Goldschmidt tolerance factor (τ) requirement. Herein, we com

Microscopic morphology independence in linear absorption cross-section of CsPbBr3 nanocrystalsMicroscopic morphology independence in linear absorption cross-section of CsPbBr3 nanocrystals

Multiple morphologies of colloidal perovskite nanocrystals (NCs) diversify their optical and electronic properties. Among them, the linear absorption cross-section (σ) is a primary parameter to determine their intrinsic photophysical features, and consequently, application potential. Herein, three morphologies of all-inorganic hybrid colloidal perovskite CsPbBr3 NCs, nanocubes (NBs), nanoplatelets

Tuning Photoinduced Electron Transfer in POM-Bodipy Hybrids by Controlling the Environment : Experiment and Theory

The optical and electrochemical properties of a series of polyoxometalate (POM) oxoclusters decorated with two bodipy (boron-dipyrromethene) light-harvesting units were examined. Evaluated here in this polyanionic donor-acceptor system is the effect of the solvent and associated counterions on the intramolecular photoinduced electron transfer. The results show that both solvents and counterions ha

Coherent Multidimensional Spectroscopy: Development of Efficient Data Acquisition and Analyses of Quantum Dot 2D Spectra

Coherent multidimensional spectroscopy (CMDS) is the most complete nonlinear optical technique based on the interaction of multiple short laser pulses with matter. It has grown to play a significant role in studies of optoelectronic materials and pigment protein complexes. In this work we apply CMDS to investigate electronic excitations and their dynamics in semiconductor nanocrystals, so called q

SinoPedia—A Linked Data Services platform for decentralized knowledge base

Knowledge bases are largely developed and utilized in academic and industrial fields, such as DBPedia, VIAF, LoC, Getty, and which are published in the Linked Data format. However, if you want to view different resources on these knowledge bases, you have to switch between different web pages from these resources. Therefore, we proposed a decentralized data hub named SinoPedia, which consists of s

Spray coated colloidal quantum dot films for broadband photodetectors

A technique for scalable spray coating of colloidal CdSeTe quantum dots (QDs) for photovoltaics and photodetector applications is presented. A mixture solvent with water and ethanol was introduced to enhance the adhesive force between QDs and the substrate interface. The performance of the detector reached the highest values with 40 spray coating cycles of QD deposition. The photodetectors without

Classification of dark states in multilevel dissipative systems

Dark states are eigenstates or steady states of a system that are decoupled from the radiation. Their use, along with associated techniques such as stimulated Raman adiabatic passage, has extended from atomic physics, where it is an essential cooling mechanism, to more recent versions in the condensed phase where it can increase the coherence times of qubits. These states are often discussed in th

Wideband RCS reduction based on a simple chessboard metasurface

To avoid being detected by radar, it is necessary to reduce stealthy military platforms' radar cross section (RCS). The operation of overlaying the metasurface (MS) on the targets is a good solution. A simple chessboard MS structure that can achieve low RCS over a large bandwidth is proposed. Only one unit cell is used to construct the MS. First, the unit cell working in 0.5 and 1−λ modes is desig

Flexible Density-based Multipath Component Clustering Utilizing Ground Truth Pose

Accurate statistical characterization of electromagnetic propagation is necessary for the design and deployment of radio systems. State-of-the-art channel models such as the Enhanced COST 2100 Channel Model utilize the concept of clusters of multipath components, and characterize channels by their inter- and intra-cluster statistics. Automatic clustering algorithms have been proposed in literature

Methodological concerns using intra-cortical pins to measure tibiofemoral kinematics

The complexity of human tibiofemoral joint motion is now better understood with the advancement of new methodologies to measure tibiofemoral kinematics in vivo. Marker clusters anchored to stainless steel bone pins inserted directly into the femur and tibia provide the most sensitive and accurate means for directly measuring skeletal tibiofemoral joint motion. Despite its invasiveness, this techni

Hygiene may attenuate selection for antibiotic resistance by changing microbial community structure

Good hygiene, in both health care and the community, is central to containing the rise of antibiotic resistance, as well as to infection control more generally. But despite the well-known importance, the ecological mechanisms by which hygiene (or other transmission control measures) affect the evolution of resistance remain to be elucidated. Using metacommunity ecology theory, we here propose that

An empirically based model of software prototyping : a mapping study and a multi-case study

Context: Prototyping is an established practice within product and user interface design that is also used as a requirements engineering (RE) practice within agile development. Even so, there is a lack of theory on prototyping.Aims: Our main research objective is to support practitioners in improving on their prototyping practices.Method: We have designed a model that describes key aspects of the

Software selection in large-scale software engineering: A model and criteria based on interactive rapid reviews

Context: Software selection in large-scale software development continues to be ad hoc and ill-structured. Previous proposals for software component selection tend to be technology-specific and/or do not consider business or ecosystem concerns.Objective: Our main aim is to develop an industrially relevant technology-agnostic method that can support practitioners in making informed decisions when s

Industry-academia collaboration for realism in software engineering research : Insights and recommendations

Context: Effective industry-academia collaboration may increase software engineering research relevance by increased realism, yet very challenging for reasons like confidentiality concerns, different objectives and priorities. Objective: We analyse industry-academia collaboration scenarios based on our own experiences as Ph.D. student and supervisor, and provide insights and recommendations to fac

Large Intelligent Surface Measurements for Joint Communication and Sensing

Multiple concepts for future generations of wireless communication standards utilize coherent processing of signals from many distributed antennas. Names for these concepts include distributed MIMO, cell-free massive MIMO, XL-MIMO, and large intelligent surfaces. They aim to improve communica- tion reliability, capacity, as well as energy efficiency and provide possibilities for new applications t

Quad-element LTE hidden car roof antenna system

This work presents the systematic design and optimization of a compact quad-element MIMO antenna system in a roof cavity for the expected channel behavior at a 700 MHz LTE band. Beginning with a standard low-profile antenna element, the desired radiation pattern is synthesized by structural modification. The configuration for a quad-element design is then optimized. The results show that the propo

Deep learning prediction models based on EHR trajectories : A systematic review

BACKGROUND: Electronic health records (EHRs) are generated at an ever-increasing rate. EHR trajectories, the temporal aspect of health records, facilitate predicting patients' future health-related risks. It enables healthcare systems to increase the quality of care through early identification and primary prevention. Deep learning techniques have shown great capacity for analyzing complex data an

Tumour origin, diagnostic accuracy and histopathological evaluation in patients with periampullary cancer : nationwide cohort study

Background: The prevalence of different periampullary cancers (pancreatic ductal adenocarcinoma, distal cholangiocarcinoma, ampullary cancer and duodenal cancer) is heterogeneous in the literature. During the 2010s, a standardized histopathological protocol for pancreatoduodenectomy specimens based on axial slicing was adopted in Sweden. The present study sought to provide information about periam