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The crystal structure of superoxide dismutase (SOD) from the hyper thermophile Sulfolobus solfataricus has been determined at 2.3 Å resolution by molecular replacement and refined to a crystallographic R-factor of 16.8 % (Rfree 19.8 %). The crystals belong to the space group C2 (a = 76.3 Å, b = 124.3 Å,c = 60.3 Å, β = 128.8°) with two identical monomers in the asymmetric unit. The monomer has a mo
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A phase of approximate composition SbVO4 has been reported in the literature as a key component in new catalysts for the ammoxidation of propane to acrylonitrile. Sb0.92V0.92O4 was prepared by heating equimolar amounts of Sb2O3 and V2O5 in air at 1073 K for 2 hr. The chemical composition was determined by thermogravimetry and energy dispersive X-ray microanalysis. The crystal structure at 293 K wa
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We study electron spin transport and the spin Hall effect in a quantum waveguide in the presence of Rashba spin-orbit interaction (SOI) and a homogeneous in-plane magnetic field, as well as the energy dispersion relation and spin polarization properties of the electron states in the corresponding infinite system. A general expression for the spin polarization of the outgoing flux, resulting from a
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Romania has for a long time been lacking good palaeoenvironmental records, particularly for the Late Quaternary. A chronological framework had been nearly absent and the vegetation development had been reconstructed entirely from pollen data. Data sets from this part of Europe are important for assessing the spatial variability of past vegetation and climatic changes and to reconstruct tree migrat
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Cold protective clothing was studied in 2 European Union projects. The objectives were (a) to examine different insulation calculation methods as measured on a manikin (serial or parallel), for the prediction of cold stress (IREQ); (b) to consider the effects of cold protective clothing on metabolic rate; (c) to evaluate the movement and wind correction of clothing insulation values. Tests were ca
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We present the first study of dipole and quadrupole moments of liquid water calculated using coupled cluster/molecular mechanics (COMM) methods. CUMM methods are used to calculate the total dipole moment of the water dimer and the results are compared to the corresponding ab initio quantum mechanical calculations. For liquid water we find that the introduction of polarization effects are very impo
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From the general triple angular correlation of gamma-radiations from axially symmetric oriented nuclear states the limit of double correlations with unobserved intermediate transitions is derived. Expressions for DCO ratios are obtained for a detector geometry in which the OSIRIS array is placed perpendicular to the beam direction and an additional Ge detector is positioned close to the beam axis.
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Females of the common frog, Rana temporaria, spawn synchronously at communal breeding sites, forming a communal egg mass of individual spawn clumps. A total of four spawning sites were studied. In the centre of the communal egg mass, daily maximum temperature was higher and minimum temperature lower than further out. Spawn clumps in the centre of the communal egg mass developed faster than single
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Kinetic properties of the monomeric enzyme dUTPase from herpes simplex virus type 1 (HSV) were investigated and compared to those previously determined for homotrimeric dUTPases of bacterial and retroviral origins. The HSV and Escherichia coli dUTPases are equally potent as catalysts towards the native substrate dUTP with a kcat/KM of about 107 M-1 s-1 and a KM of 0.3 μM. However, the viral enzyme
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BACKGROUND AND AIMS: Orlistat, a lipase inhibitor, strongly inhibits the activities of all gastric/pancreatic lipases except pancreatic phospholipase A(2)in vitro. In clinical use, for obesity treatment, it induces a variable degree of weight loss and steatorrhoéa. The aim of this study was to examine the degree of in vivo inhibition of individual gastric/pancreatic lipases by Orlistat in man, whe
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We report on the visualization of the penetration of sunscreen formulations containing TiO2 nanoparticles (about 20 nm primary particle size) into hair follicles of both human and porcine skin using the complementary methods of ion microscopy (PIXE, RBS, STIM) and autoradiography. Particles were found as deep as approx. 400 pin in the follicle, obviously introduced mechanically rather than by a di
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The scheme of concepts we employ in daily life to explain intentional behaviour form a belief-desire model (BD model), in which motivating states are sorted into two suitably broad categories. The BD model embeds a philosophy of action, i.e. a set of assumptions about the ontology of motivation with subsequent restrictions on psychologising and norms of practical reason. A comprehensive critique o
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In this study, we introduce the architecture and style of sedimentation of two outwash fans in front of the Myrdalsjokull ice cap, central south Iceland, that broaden different types of ice-marginal sedimentation. At Kotlujokull, a southeastern outlet of the ice cap, fan formation was monitored from the late 1970s to 2002; thus, the style of sedimentation is well understood and the relationship to
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A new beam line for generating a sub-micron beam spot for high-resolution nuclear microprobe applications has been constructed at the Lund Nuclear Microprobe facility. The design and construction of the beam line, the quality test of the four high precision Oxford OM-52 Quadrupole magnets by the grid shadow method and the beam scanning system are presented in this paper. The beam line is designed
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"The paper treats the problem of frost resistance as a general problem for all porous materials. The difference between the new way of defining critical degree of saturation (as a materials constant) and the usual way (as functions of a combination of properties of material and environment) is discussed. Possible definitions of moisture conditions are provided. By comparison of the critical degree
