Strain and Composition Dependencies of the Near-Band-Gap Optical Transitions in Monoclinic (AlxGa1−x)2O3 Alloys with Coherent Biaxial In-Plane Strain on Ga2O3(010)
The bowing of the energy of the three lowest band-to-band transitions in β−(AlxGa1−x)2O3 alloys is resolved using a combined density-functional theory (DFT) and generalized spectroscopic ellipsometry approach. The DFT calculations of the electronic band structure of both β−Ga2O3 and θ−Al2O3 allow the linear portion of the energy shift in the alloys to be extracted, and provide a method for quant