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Fe(II) and Fe(IV)-oxo complexes of a ligand based on the pentadentate N4Py framework have been investigated for oxidation of aliphatic compounds. The ligand N-(isoquinolin-3-ylmethyl)-1,1-di(pyridin-2-yl)-N-(pyridin-2-ylmethyl)methanamine (N3Py-IQ) and the complex [Fe(II)(-NCMe)(-N3Py-IQ)]2+ have been successfully synthesised and characterized. The 1H NMR spectrum of the low spin d6 [Fe(II)(-NCMe)
