Balance between surface complexation and surface phase transformation at the alumina/water interface
This paper synthesizes and expands on the results of a recent series of investigations aimed at characterizing the interactions of orthophosphate, phenylphosphonate, and clodronate ions with hydrous alumina surfaces. The paper shows that gamma-Al2O3 is a thermodynamically unstable substance in water, which undergoes a (surface) phase transformation into bayerite, beta-Al(OH)(3). Furthermore, it al
