Synthesis and Characterization of Triosmium Clusters Containing the Bidentate Ligand Ph2PCH2CH2SMe; Detection of an Unusual Isomerisation Reaction
Diphenylphosphinoethylene methyl sulfide, Ph2PCH2CH2SMe, reacts with [Os3(CO)11(NCMe)] yielding [Os3(CO)11(Ph2PCH2CH2SMe)]. Treatment of [Os3(CO)10(NCMe)2] with 1 equiv of the P,S ligand initially yields the cluster 1,2-[Os3(CO)10(-Ph2PCH2CH2SMe)], in which the phosphine and the thioether moieties coordinate to different metal atoms of the metal triangle; addition of two or more equivalents of the