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The formation of highly ordered mesoporous silica materials, using PEO-PPO-PEO amphiphilic triblock copolymers (so-called Pluronics) as structure directing agents, has been studied. The materials are formed through the addition of a silica source to a polymer solution of low concentration (2.5 wt ) under acidic conditions. The products have BET surface areas of approximately 800 m2/g. The unit cel
Osteotomy is used for correction of the altered load on the gonarthrotic knee joint. It can be performed above or below the knee. Clinical results depend on the correction after bone healing. By tibial closed wedge osteotomy (HTO), the deformity is corrected peroperatively in contrast to tibial hemicallotasis osteotomy (HCO) where the correction is performed after surgery. Comparing the two method
The Affects Towards And Perceptions Of The Self And Significant Others in Hemophiliacs and Diabetics The studies in this dissertation investigated the feelings towards and ways of perceiving the self and significant others in twenty-seven patients with hemophilia between the ages of 16-39 to discern how their perceptual-affect states are organized. Secondly, the relationship between bleeds and aff
This study has involved investigation of number of populations of the damselfly Ischnura elegans over several years, looking at frequency changes over time, morphological differences between the sexes and the morphs, differences in growth rate and development time, differences in fecundity between the morphs, and genetic differentiation between populations. I. elegans is a small annual damselfly w
Microbial activity in soil is generally assumed to be limited by carbon availability. The soil closest to roots, the rhizosphere, is therefore a zone of high microbial activity due to carbon containing substances released by the root. In this work short-term effects in the rhizosphere have been the subject of investigation. I have shown that the thymidine and leucine incorporation techniques are w
Molar mass and molar mass distribution of polymers are parameters of fundamental importance as they influence the performance of the polymer in applications. Polysaccharide derivatives are a class of polymers that have attracted significant scientific and commercial interest as they can be manufactured from a wide range of abundant sources in nature and thereby often are both cheap and biocompatib
Inhalation of air-borne microorganisms and components thereof can cause illnesses and diseases. However, lack of specific and sensitive methods for exposure assessment can pose problems in predicting health outcomes. Characterization of microbial load from indoor environments using gas chromatography-mass spectrometry (GC-MS) and/or tandem mass spectrometry (GC-MSMS) as well as various bioassays (
A number of homo- and heterodinuclear complexes have been synthesized as structural and functional models for the the active sites of phosphoesterases and soluble methane monooxygenases. The complexes are based on four new dinucleating ligands containing a central, potentially bridging, phenolate moiety. The hydrolytic activity of the complexes was examined by exploring the ability of the complexe
This thesis focuses on i) the effect of packing on the molecular geometry ii) packing arrangements of neutral Pd(II) and Pt(II) complexes iii) the trans influence in Pt(II) complexes iv) the differences in bonding in corresponding Pd(II) and Pt(II) complexes and v) the geometry of Pd(II) complexes with potential catalytic properties. Detailed three-dimensional structural information at the atomic
Organic carbon and bacteria have a high variability at different scales in the soil, and organic carbon may be a limiting factor for growth of soil bacteria. Thus, it can be expected that these co-vary at different scales in the soil. In this thesis, I have studied the spatial interaction between soil bacteria and natural and contaminant (polycyclic aromatic hydrocarbon, PAH) organic carbon. The o
Epoxy resins based on bisphenol A are well-known contact allergens and often cause occupational contact allergy. The most important allergen is the monomer diglycidyl ether of bisphenol A (DGEBA). Epoxy resins of the bisphenol F-type contain 3 isomers of the diglycidyl ether of bisphenol F; p,p'-DGEBF, o,p'-DGEBF, and o,o'-DGEBF, whereas epoxy resin(s) based on bisphenol A (DGEBA-R) contain virtua
Chemical processes are usually expensive to run. To optimise a process, we need to know how the process behaves, and this is usually accomplished by studying the process experimentally. However, experiments are very expensive, particularly if an existing plant has to shut down normal operation to conduct an experiment. A better way is to build a model and simulate the process. In order to obtain t
The aim of this thesis has been to study protein-polymer interaction and association. Two different techniques were used; Monte Carlo simulations were combined with partitioning in polymeric aqueous two-phase systems. Monte Carlo simulations have been used to evaluate the hydrophobic interaction in electrolyte solution. The results showed that monovalent salt only slightly increases the hydrophob
Harvesting changes population abundance and can affect adaptation of several life-history traits. Harvesting can also have indirect effects ? effects on non-target species and secondary effects on target species ? because interactions between species in a community determine the relevant ecological and evolutionary feedback environment. Species interactions therefore influence the effect of harves
Telomeres are specialized complexes of DNA and associated proteins that protect the ends of eukaryotic chromosomes. Although most organisms have short repeated DNA sequences at their telomeres, which are specified and maintained by the enzyme telomerase, there are a few exceptions. Dipteran insects, including the genus Chironomus (non-biting midges), lack telomerase and have atypical terminal sequ
A laser-produced plasma was generated by focusing 100 fs laser pulses, with an energy of 150 mJ, onto metal targets. The laser intensity was expected to reach 10E17 W/cm2. Radiation was emitted from the created plasma, with photon energies extending up to the MeV regime. The laser-based X-ray source was optimised, with the purpose of making it a realistic source of hard X-rays (>10 keV). Dedicated
In this thesis I study two-dimensional geometric optimization problems for which it is difficult to find efficient, exact, deterministic algorithms. All known solutions to these problems require time that is exponential in the total size of the input. The work done in this thesis is a contribution to the research directed at attacking and coping with such NP hard problems in computational geometry
Summary: For religious Sikhs, the Guru Granth Sahib is a holy scripture which enshrines ontologically divine words and the teaching and revelatory experiences of historical human Gurus. Simultaneously the Sikhs have taken the concept of a sacred scripture much further than any other religious community by treating the Guru Granth Sahib as a living Guru invested with spiritual authority and agency
Hematopoietic stem cells (HSCs) are defined by their capacity to self-renew and differentiate into all hematopoietic cell lineages. Postnatally, HSCs reside predominantly in the bone marrow and are relatively rare, but important cells because of their therapeutic potential in bone marrow transplantation protocols and in their involvement in the origin of certain leukemias. To study how various gen
