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Polymer Bound Water-Soluble Metal Phosphine Complexes-Preparation, Characterisation and Catalytic Application

Four new water-soluble phosphines have been prepared by utilising water-soluble polymers as charge carrying units. Coupling of methyl-4-(diphenylphosphino)-benzyl-amine or 4-diphenylphosphino benzaldehyde to poly-acrylic acid and poly-ethylene imine, respectively, afford the ligands PAA-PNH and PEI-PNH. Coupling of (2S,4S)-4-diphenylphosphino-2-di-phenylphosphino-methylpyrrolidine (PPM) or (R,R)-3