Structures of trans-[PtCl2(PBz3)2], trans-[PtI2(PBz3)2], trans-[Pt(NCS)2(PBz3)2] small middle dot0.5C6H6 and trans-[PdI2(PBz3)2].
A series of structures of trans-[MX(2)(PBz(3))(2)] [M = Pt, X = Cl(-); PBz(3) = tribenzylphosphine (1), I(-), trans-diiodobis(tribenzylphosphine)platinum(II) (2), and NCS(-), trans-di(thiocyanate)bis(tribenzylphosphine)platinum(II) (3); M = Pd, X = I(-), trans-diiodobis(tribenzylphosphine)palladium(II) (4)] have been characterized by X-ray crystallography. In all compounds each tribenzylphosphine