The Crystal and Molecular Structure of HOs6(CO)21(NCMe)PH2
The crystal structure of the phosphide-bridged cluster [Os6(μ-H)(CO)12(NCMe)(μ-PH2)] 4 has been determined. The cluster consists of two Os3 triangles which are linked by a PH2 moiety which is terminally bound to each triangle. The acetonitrile ligand is axially coordinated and the hydride bridges the Os---Os edge to which the phosphide moiety and the acetonitrile are coordinated. The molecular str