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Rational molecular design of anion exchange membranes functionalized with alicyclic quaternary ammonium cations

High alkaline stability is critical for polymeric anion exchange membranes (AEMs) and ionomers for use in alkaline electrochemical energy conversion and storage devices such as fuel cells, electrolyzer cells and advanced batteries. Here, we have prepared and studied ether-free polyfluorenes tethered with N,N-dimethylpiperidinium (DMP) and 6-azonia-spiro[5.5]undecane (ASU) cations, respectively, at

Asymmetric cycling of vanadium redox flow batteries with a poly(arylene piperidinium)-based anion exchange membrane

The potential application of a 50 μm thick anion exchange membrane prepared based on poly(terphenyl piperidinium-co-trifluoroacetophenone) (PTPT) is investigated for vanadium redox flow batteries (VRFBs). The PTPT exhibits a considerably lower vanadium permeation than Nafion 212. Therefore, the self-discharge duration of the VRFB based on PTPT is much longer than the VRFB based on Nafion 212. Besi

Periodontal conditions, retinopathy, and serum markers in individuals with type 1 diabetes

BACKGROUND: The prevalence of diabetes is high and increasing. Periodontitis has been identified as a risk factor in both type 1 and 2 diabetes. The study purpose was to assess periodontal conditions, retinopathy, and serum glutamic acid decarboxylase antibody (GADA) titers in relation to retinopathy in individuals with Type 1 Diabetes (T1D).METHODS: The study is a case series. Adult individuals w