Dielectric Interpretation of Specificity of Ion Pairing in Water
We present a dielectric continuum model that, at a semiquantitative level, explains why ion pair formation in water is favored by like-sized ions over unlike-sized pairs. Using both classical and ab initio continuum approaches, we show that the now well-established empirical rule, the so-called “law of matching water affinities”, can be rationalized in terms of ion solvation. Namely, pairing of di