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Oleylamine is widely used in nanomaterial and metal-halide perovskite synthesis. Impurities in commercially available oleylamine reagents are identified, purification procedures are explained, beneficial effects on lead chloride/oleylamine mixtures are documented, and impacts on materials synthesis are discussed. Suspensions of 0.12 mole fraction PbCl2 , PbBr2 , and PbI2 in purified, dried, and f
Giuliano and Spilimbergo (2014) show that individuals who experienced a recession when young are more likely to favor redistribution in the short and long run. We revisit their analysis in three ways. First, we conduct a narrow replication in the General Social Survey and the World Values Survey; we successfully replicate the original results for outcomes that directly measure preferences for redi
The goal of a medico-legal autopsy is primarily to determine the cause and manner of death. To this end, the pathologist often uses auxiliary analyses, including histology. However, the utility of routine histology in all medico-legal autopsies is unknown. Earlier studies on the utility of routine histology have shown inconsistent effects, with some studies recommending it and others rejecting it.
The formation of cesium lead bromide (CsPbBr3 ) nanocrystal superlattices (NC SLs) is accompanied by a red shift in the NC photoluminescence (PL). The values of the PL red shift reported in the literature range from none to 100 meV without unifying explanation of the differences. Using a combination of confocal PL microcopy and steady-state optical spectroscopies we found that an overall PL red s
Fully inorganic cesium lead halide perovskite (CsPbX3) nanocrystals (NCs) have been extensively studied due to their excellent optical properties, especially their high photoluminescence quantum yield (PLQY) and the ease with which the PL can be tuned across the visible spectrum. So far, most strategies for synthesizing CsPbX3 NCs are highly sensitive to the processing conditions and ligand combi
We report the synthesis of various binary and ternary inorganic and hybrid organic-inorganic iodide nanocrystals (NCs) starting from molecular iodine (I2). The synthesis described herein utilizes a reaction between I2 and oleylamine, which results in oleylammonium iodide, an iodide precursor that can be directly used in the preparation of iodide-based NCs. The generality of the synthesis was demon
We show here the first colloidal synthesis of double perovskite Cs2AgInCl6 nanocrystals (NCs) with a control over their size distribution. In our approach, metal carboxylate precursors and ligands (oleylamine and oleic acid) are dissolved in diphenyl ether and reacted at 105 °C with benzoyl chloride. The resulting Cs2AgInCl6 NCs exhibit the expected double perovskite crystal structure, are stable
In laser spectroscopy, high photon flux can perturb the sample away from thermal equilibrium, altering its spectroscopic properties. Here, we describe an optical beam scanning apparatus that minimizes repetitive sample excitation while providing shot-to-shot sample exchange for samples such as cryostats, films, and air-tight cuvettes. In this apparatus, the beam crossing point is moved within the
Femtosecond two-dimensional Fourier transform spectroscopy is used to determine the static bandgap inhomogeneity of a colloidal quantum dot ensemble. The excited states of quantum dots absorb light, so their absorptive two-dimensional (2D) spectra will typically have positive and negative peaks. It is shown that the absorption bandgap inhomogeneity is robustly determined by the slope of the nodal
In experiments with high photon flux, it is necessary to rapidly remove the sample from the beam and to delay re-excitation until the sample has returned to equilibrium. Rapid and complete sample exchange has been a challenge for air-sensitive samples and for vibration-sensitive experiments. Here, a compact spinning sample cell for air and moisture sensitive liquid and thin film samples is describ
Pump-probe polarization anisotropy measurements with 15 fs pulses are employed to investigate the electronic structure of PbS quantum dots. The initial anisotropy at the bandgap is anomalously low (<0.1) and suggests large electronic couplings.
The first low-energy Coulomb-excitation measurement of the radioactive, semi-magic, two proton-hole nucleus 206Hg, was performed at CERN's recently-commissioned HIE-ISOLDE facility. Two γ rays depopulating low-lying states in 206Hg were observed. From the data, a reduced transition strength B(E2; 2+1 → 0+1) = 4.4(6) W.u. was determined, the first such value for an N=126 nucleus south of 208Pb, whi
A recent case of a flawed medical AI system that was backed by public funding provides an opportunity to discuss the impact of government policies and regulation in AI.
Multi-gigawatt-scale hydrogen production by water electrolysis is central in the green transition when it comes to storage of energy and forming the basis for sustainable fuels and materials. Alkaline water electrolysis plays a key role in this context, as the scale of implementation is not limited by the availability of scarce and expensive raw materials. Even though it is a mature technology, th
This article addresses the development under Xi Jinping of ideological and political education at the university level. It provides an overview of trends among youth, major policies and recent developments, and an analysis of how ideological and political education is organised at universities and incorporated into the curricula. It also argues that ideological and political education targeting yo
