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Boron-doped diamond (BDD) films were synthesized via microwave plasma-enhanced chemical vapor deposition at five boron-to-carbon ratios to investigate dopant effects on perfluorooctanoic acid (PFOA) electrooxidation and electrode stability. Raman spectroscopy revealed that excessive boron (≥10k ppm) produced sp²-rich regions indicative of structural degradation. Electrodes optimized at ∼10k ppm bo
