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Lamellar Microdomains of Block-Copolymer-Based Ionic Supramolecules Exhibiting a Hierarchical Self-Assembly

Based on a parent diblock copolymer of poly(styrene)-b-poly(methacrylic acid), PS-b-PMAA, linear-b-amphiphilic comb (L-b-AC) ionic supramolecules [Soft Matter 2013, 9, 1540-1555] are synthesized in which the poly(methacrylate) backbone of the ionic supramolecular AC-block is neutralized by alkyl (Cn; n = 8, 12, and 16) trimethylammonium counterions (i.e., side chains) at various ion (pair) fractio

High p(T) direct photon and pi(0) triggered azimuthal jet correlations and measurement of k(T) for isolated direct photons in p plus p collisions at root s=200 GeV

Correlations of charged hadrons of 1< p(T) < 10 Gev/c with high pT direct photons and pi(0) mesons in the range 5< p(T) < 15 Gev/c are used to study jet fragmentation in the gamma + jet and dijet channels, respectively. The magnitude of the partonic transverse momentum, k(T), is obtained by comparing to a model incorporating a Gaussian kT smearing. The sensitivity of the associated charged hadron

The role of input frequency and semantic transparency in the acquisition of verb meaning: Evidence from placement verbs in Tamil and Dutch

We investigate how Tamil- and Dutch-speaking adults and 4- to-5-year-old children use caused posture verbs (‘lay/stand a bottle on a table’) to label placement events in which objects are oriented vertically or horizontally. Tamil caused posture verbs consist of morphemes that individually label the causal and result subevents (nikka veyyii ‘make stand’; paDka veyyii ‘make lie’), occurring in situ

Measurement of the forward-backward asymmetry of electron and muon pair-production in pp collisions at root s=7 TeV with the ATLAS detector

This paper presents measurements from the ATLAS experiment of the forward-backward asymmetry in the reaction pp -> Z/gamma* -> l(+)l(-), with l being electrons or muons, and the extraction of the effective weak mixing angle. The results are based on the full set of data collected in 2011 in pp collisions at the LHC at root s = 7 TeV, corresponding to an integrated luminosity of 4.8 fb(-1). The mea

Reaction behavior and evolution of phases during the sintering of Ta–Al powder mixtures

Intermetallic compounds based on tantalum aluminides are of considerable interest in various industrial applications. In this work, the formation of tantalum aluminides has been studied in elemental powder mixtures containing 25, 50 and 66.7 at% Ta. A differential scanning calorimeter (DSC) was used to heat the samples up to 1500 K at 15 K min−1. Phase evolution was studied by heating a few sample

Source apportionment of the carbonaceous aerosol in Norway - quantitative estimates based on C-14, thermal-optical and organic tracer analysis

In the present study, source apportionment of the ambient summer and winter time particulate carbonaceous matter (PCM) in aerosol particles (PM1 and PM10) has been conducted for the Norwegian urban and rural background environment. Statistical treatment of data from thermal-optical, C-14 and organic tracer analysis using Latin Hypercube Sampling has allowed for quantitative estimates of seven diff

In Vitro Selection of RNA Aptamers Directed Against Protein E: A Haemophilus influenzae Adhesin. : a Haemophilus influenzae adhesin

Protein E (PE) of Haemophilus influenzae is a highly conserved ubiquitous surface protein involved in adhesion to and activation of epithelial cells. The host proteins-vitronectin, laminin, and plasminogen are major targets for PE-dependent interactions with the host. To identify novel inhibitory molecules of PE, we used an in vitro selection method based on systematic evolution of ligands by expo

Competitive adsorption involving phosphate and benzenecarboxylic acids on goethite-Effects of molecular structures

The competitive adsorption between phosphate and either one of seven benzenecarboxylates (benzoate, phthalate, trimellitate, trimesoate, hemimellitate, pyromellitate, and mellitate) on the surfaces of fine-particulate goethite (alpha-FeOOH) was investigated as a function of pH. The series of ligands contained Molecules with an increasing number of functional groups as well as three structural isom

Comorbidity and health-related quality of life in patients with severe chronic obstructive pulmonary disease attending Swedish secondary care units

Introduction: Our understanding of how comorbid diseases influence health-related quality of life (HRQL) in patients with chronic obstructive pulmonary disease (COPD) is limited and in need of improvement. The aim of this study was to examine the associations between comorbidities and HRQL as measured by the instruments EuroQol-5 dimension (EQ-5D) and the COPD Assessment Test (CAT). Methods: Infor

Long-Term Cognitive Sequelae After Pediatric Brain Tumor Related to Medical Risk Factors, Age, and Sex

BACKGROUND: Young age at diagnosis and treatment with cranial radiation therapy are well studied risk factors for cognitive impairment in pediatric brain tumor survivors. Other risk factors are hydrocephalus, surgery complications, and treatment with intrathecal chemotherapy. Female gender vulnerability to cognitive sequelae after cancer treatment has been evident in some studies, but no earlier s

Protein kinase A (PKA) pathway is functionally linked to androgen receptor (AR) in the progression of prostate cancer.

OBJECTIVES: In the present study, we investigated whether the cyclic adenosine monophosphate (cAMP)-activated protein kinase A (PKA) pathway may regulate the expression of AR and prostate-specific antigen (PSA) and whether there is a correlation between the expression of cAMP/PKA-associated genes and androgen receptors (ARs) in patients with prostate cancer (CaP). MATERIALS AND METHODS: The functi

Measurements of occupancy levels in multi-family dwellings-Application to demand controlled ventilation

The occupancy level of dwellings is an important parameter to know to determine the energy efficiency, energy use and indoor air quality, especially in low-energy buildings where the user-related energy uses, such as household electricity and domestic hot water heating, are significant parts of the energy balance in a building. For residential buildings, there is a lack of occupancy level data, wh

Unveiling systematic biases in the 1D LTE excitation-ionization balance of Fe for FGK stars: a novel approach to determination of stellar parameters

We present a comprehensive analysis of different techniques available for the spectroscopic analysis of FGK stars and provide a recommended methodology which efficiently estimates accurate stellar atmospheric parameters for large samples of stars. Our analysis includes a simultaneous equivalent width analysis of Fe I and Fe II spectral lines, and for the first time, utilizes on-the-fly non-local t

Physiological mechanisms mediating costs of immune responses: what can we learn from studies of birds?

Activating the immune system has associated fitness costs, both immediate costs in the form of reduced current reproduction and long-term costs in the form of reduced life span and future reproduction. This indicates that immune system activation can be an important agent in life history trade-offs. In this review, we evaluate the importance of four currencies generally considered as potential med

Changes in amorphous silica sequestration with eutrophication of riverine impoundments

The effect of eutrophication on particulate amorphous silica (ASi) sequestration was isolated and quantified in Lake St. Croix and Lake Pepin, two natural, human-impacted impoundments of the upper Mississippi River. In contrast to impoundments behind engineered dams, where silica (Si) fluxes may be changed by various aspects of dam construction, these two riverine lakes have long (9,000+ years) se

Diabetes and Onset of Natural Menopause: Results From the European Prospective Investigation Into Cancer and Nutrition EDITORIAL COMMENT

The age at natural menopause (ANM) in the Western world ranges from 40 to 60 years, with an average onset of 51 years. The exact mechanisms underlying the timing of ANM are not completely understood. Both genetic and environmental factors are involved. The best-established environmental factor affecting ANM is smoking; menopause occurs 1 to 2 years earlier in smokers. In addition to genetic and en