Thermodynamic and spectroscopic studies of cadmium(II)-N-(phosphonomethyl)glycine (PMG) complexes
Speciation and equilibria in the H+-Cd2+-N-(phosphonomethyl)glycine (PMG, H3L) system have been studied in 0.1 M Na(Cl) medium at 25.0 degreesC. Formation constants for a series of mononuclear complexes, CdHL, CdL-, CdL24- and CdL(OH)(2)- were determined from potentiometric titrations. The structures of the predominating species CdL-, and CdL24- in solution were investigated using EXAFS and IR spe
