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SynopsisReduction of gold(III) complexes by thiocyanate takes place via rapid substitutions at gold(III), followed by intramolecular, slower reductive elimination through attack by outer-sphere thiocyanate. A transition state with an S−S interaction between attacking and coordinated thiocyanate is suggested for the redox process.AbstractAbstract ImageKinetics for reactions between thiocyanate and SynopsisReduction of gold(III) complexes by thiocyanate takes place via rapid substitutions at gold(III), followed by intramolecular, slower reductive elimination through attack by outer-sphere thiocyanate. A transition state with an S−S interaction between attacking and coordinated thiocyanate is suggested for the redox process.AbstractAbstract ImageKinetics for reactions between thiocyanate and

This article presents the results of a study where the effect of five window glazing types on daylight quality was investigated using a scale model (1:6) of a room with a single, south east-oriented window exposed to the natural sky. The space studied simulated a typical, fully furnished living room. A total of 30 research subjects took part in the experiment, observed the room and filled question

An atmospheric pressure aerosol-based wet thin film coating technique called the nFOG is characterized and applied in polymer film coatings. In the nFOG, a fog of droplets is formed by two air-assist atomizers oriented toward each other inside a deposition chamber. The droplets settle gravitationally and deposit on a substrate, forming a wet film. In this study, the continuous deposition mode of t

People with repeated rapid meal ingestion have been reported to have increased risk of insulin resistance, impaired glucose tolerance and obesity. To explore whether speed of eating a breakfast influences the postprandial rise of glucose, insulin and the incretin hormones, 24 healthy subjects (12 men and 12 women, mean age 62 years) ingested a standardized solid breakfast consisting of 524 kcal (6

NanoMAX is a hard x-ray nanoimaging beamline at the new Swedish synchrotron radiation source MAX IV that became operational in 2016. Being a beamline dedicated to x-ray nanoimaging in both 2D and 3D, NanoMAX is the first to take full advantage of MAX IVs exceptional low emittance and resulting coherent properties. We present results from the first experiments at NanoMAX that took place in December

QmeQ is an open-source Python package for numerical modeling of transport through quantum dot devices with strong electron-electron interactions using various approximate master equation approaches. The package provides a framework for calculating stationary particle or energy currents driven by differences in chemical potentials or temperatures between the leads which are tunnel coupled to the qu

This work provides new insights into the presence of 239Pu, 240Pu, 241Pu, and 236U in the Southern Hemisphere through the study of peat bog cores from marshlands in Madagascar (19°S). 210Pb, 238Pu and 239+240Pu activities were characterized by alpha spectrometry in previous studies. Here, Pu from alpha-spectrometry discs corresponding to 10 peat-bog cores (85 samples) was reassessed for the aim of

An early and accurate diagnosis of Alzheimer's disease (AD) is required to initiate symptomatic treatment with currently approved drugs and will be of even greater importance if disease modifying compounds in development display a clinical effect. Protein profiles of human cerebrospinal fluid samples from AD patients (n = 95) and population-based healthy controls (n = 72) were analyzed by SELDI-TO

An algorithm specific digital signal processor is a powerful alternative to a general purpose signal processor for demanding specifications such as high throughput, low power, small size, etc. These properties are achieved as the processor architecture is tailored to the algorithm as opposed to the general purpose architecture which must suit a wide range of algorithms. The increased performance i

Popular Abstract in Swedish Datorsimuleringar, konsten att modellera verkliga eller tänkta händelser med hjälp av en dator och ett lämpligt simuleringsprogram, har blivit ett dominerande verktyg inom tekniska och naturvetenskapliga områden, likväl inom akademiska och industriella tillämpningar. Trots att experimentella studier har ett vedertaget erkännande inom diverse forskningsstudier har den snThis thesis concerns the study of Fluid-Structure interaction phenomena among deforming and (non-deforming) vibrating objects under unsteady fluid fl ow exposures. This multi-physical phenomenon is widely encountered in real-life situations and therefore it is of significant importance to understand the underlying physics. The trend is that both industrial and research facilities aim for developi

Popular Abstract in Swedish Målet avhandlingen har varit att undersöka möjligheten att bygga en kvantdator i kristaller dopade med joner av sällsynta jordartsmetaller. Det har visat sig att sådana joner har en väldigt lång livstid, vilket är en förutsättning för de typer av experiment som har utförts i den här avhandlingen. För att ytterliggare förhindra att de känsliga tillstånden i jonerna störsThis thesis describes a number of coherent processes, such as quantum information processing, superradiance and electromagnetically induced transparency, which have been experimentally implemented using rare-earth-ion-doped crystals. The rare-earths are a class of elements that have in common, an atomic structure that allows for very long lifetimes as well as coherence times, both on optical trans

The objective of this study is to reach a better understanding of accidents on Swedish roads involving tractors and to suggest ways of preventing them. In an earlier study we analyzed police-reported fatal accidents and accidents that led to physical injuries from 1992 to 2005. During each year of this period, tractors were involved in 128 traffic accidents on average, an average of 7 people were

The growth and optoelectronic properties of core-shell nanostructures are influenced by the strain induced by the lattice mismatch between core and shell. In contrast with planar films, nanostructures contain multiple facets that act as independent substrates for shell growth, which enables different relaxation mechanisms. In this study, X-ray diffraction data are presented that show that InGa1-N

Objective: The proteoglycan decorin stabilizes collagen whereas biglycan and hyaluronan disrupt well-organized collagen. The aim was to compare hyaluronan and proteoglycans in human fetal membranes obtained before and after spontaneous labour at term. Study design: Prelabour samples of fetal membranes (N = 9) were obtained from elective caesarean sections and regionally sampled from over the cervi

Five acute leukaemia or highly malignant lymphoma patients at a hospital in southern Sweden were interviewed about their daily living problems, their coping strategies and their opinions about the nursing care they received during the active phase of their treatment. In addition the EORTC QLQ-C30, the Global Life Quality and the Sense of Coherence scales were administered. The data were analysed f

Popular Abstract in English “We are not free in this area.” This is what the iNduna, a traditional leader at KwaDapha, shared with me when we first met in August 2011. KwaDapha is a small rural community at Bhanga Nek, Kosi Bay, in northern KwaZulu-Natal/Maputaland – one of the most scenic areas on the South African coastline. Kosi Bay falls within the Coastal Forest Reserve section of the iSimaIn the past several decades under a growing influence of ecological modernisation, various assumed ‘win-win’ approaches to protected area conservation and poverty alleviation have been introduced all over the world, especially in resource-rich developing countries. Yet protected area conservation is an inherently political process, and the goals are often not achieved. There are concerns about com

As a result of the globalisation of the world economy, many enterprises that previously confined their business activities to national markets are now focusing on broader international markets, thus forming the basis for the establishment of global enterprises. In addition to the extension of markets, these global companies also seek cost reductions through scale economics in logistics, marketing,