Mechanisms for Acceleration of Halide Anation Reactions of Platinum(IV) Complexes. REOA versus Ligand Assistance and Platinu(II) Catalysis without Central Ion Exchange
Chloride anation of trans-Pt(CN)4ClOH2− has been studied with and without Pt(CN)42− present at 25.0 °C by use of stopped-flow and conventional spectrophotometry and a 1.00 M perchlorate medium. The rate law in the absence of Pt(CN)42− is compatible with a chloride assistance via an intermediate of the type Cl-Cl-Pt(CN)4···OH22−, in which the reactivity of the aqua ligand is enhanced due to a partiChloride anation of trans-Pt(CN)4ClOH2− has been studied with and without Pt(CN)42− present at 25.0°C by use of stopped-flow and conventional spectrophotometry and a 1.00 M perchlorate medium. The rate law in the absence of Pt(CN)42− is compatible with a chloride assistance via an intermediate of the type Cl-Cl-Pt(CN)4···OH22−, in which the reactivity of the aqua ligand is enhanced due to a partia
