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Popular Abstract in Swedish Vid vattenabsorption i en polymer antas vattenmolekylerna röra sig genom polymeren via små kaviteter, som inte upptas av polymermolekylerna och dess termiska vibrationer. Den ej upptagna volymen, som de små kaviteterna representerar kallas fri volym. Storleken på kaviteterna liksom andra egenskaper hos polymeren såsom andelen kristallin fas ändras kontinuerligt i takt mDuring moisture uptake in polymers, the diffusion of the water molecules is believed to occur via unoccupied voids. These voids are called free volume cavities and their sizes are continuously altered when the moisture content in the polymer is enhanced. Not only the free volume cavity sizes, but also other polymer properties such as the degree of crystallinity, are changed as a consequence of moi