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Oxidation of dissolved sulfur dioxide, SO2·nH2O, HSO3– and SO32–, by hexaaquathallium(III) has been studied in acidic aqueous solution with ionic strength 1.0 mol dm–3 at 25 °C. The stoichiometry of the reaction has been determined: [Tl(H2O)6]3++ SO2(aq)+ 2H2O →[Tl(H2O)6]++ HSO4–+ 3H+. The kinetics has been studied by use of stopped-flow spectrophotometry under pseudo-first-order conditions with eOxidation of dissolved sulfur dioxide, SO2·nH2O, HSO3– and SO32–, by hexaaquathallium(III) has been studied in acidic aqueous solution with ionic strength 1.0 mol dm–3 at 25 °C. The stoichiometry of the reaction has been determined: [Tl(H2O)6]3++ SO2(aq)+ 2H2O →[Tl(H2O)6]++ HSO4–+ 3H+. The kinetics has been studied by use of stopped-flow spectrophotometry under pseudo-first-order conditions with e
