Preparation and characterisation of aggregating comblike poly(propylene oxide)
Poly(propylene oxide)s with a comblike architecture were prepared by using an ethylene-vinyl alcohol copolymer as a macroinitiator for anionic graft polymerisation of propylene oxide. The densely grafted polymers were subsequently modified by capping the terminal hydroxyl groups with hexadecanoyl chloride to produce aggregating polymers. Dilute solution viscometry showed that the hydroxyl and hexa