α-amino radicals induced by an Fe(III) N heterocyclic carbene photosensitizer
Photoredox catalysis with 1st row transition metals is an expanding, but challenging field of research. Using iron complexes as useful catalysts is especially difficult due to low exited state lifetimes and the need for suitable redox-potentials of the involved ground and excited states. The use of strongly σ-donating NHC-ligands led to exited state lifetimes in the pico- and nanosecond region, wh
