Isotope effects in the reactions of chloroform isotopologues with Cl, OH, and OD
The kinetic isotope effects in the reactions of CHCl3, CDCl 3, and 13CHCl3 with Cl, OH, and OD radicals have been determined in relative rate experiments at 298 ± 1 K and atmospheric pressure monitored by long path FTIR spectroscopy. The spectra were analyzed using a nonlinear least-squares spectral fitting procedure including line data from the HITRAN database and measured infrared spectra as ref