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H+ modulated charge-transfer in photoexcited covalent polyoxometalate-bodipy conjugates is described. The hybrid organic/inorganic molecular photoactive dyads are based on Keggin-type polyoxometalates (POMs, where KM = [PM11O39] and M = Mo or W) covalently grafted via an organotin linker to a bodipy (BOD) photosensitizer. The relative potentials of the photosensitizer and POM are aligned such that

Twenty years since the adoption of UN Security Council Resolution 1325 there is an almost unanimous call for an increased number of uniformed women in peace operations from policy-makers and multilateral organizations. This continuous push for the inclusion of more women is often justified by arguments about an increased operational effectiveness related to women's ‘added value’: both implicitly a

Nils-Eric Sahlin och Sylvia Schwaag Serger diskuterar i kapitel tre hur forskare har interagerat med beslutsfattare under krisen och presenterar principer som syftar till att förbättra samspelet mellan vetenskap och politik.

This study focuses on soldiers returning from peacekeeping missions and the challenges they experience adapting to the home environment in the postdeployment phase. The article focuses on South African peacekeepers returning from missions in Darfur/Sudan, the Democratic Republic of Congo, and Burundi. Interviews with 50 South African peacekeepers on the challenges they face in terms of their homec

Taking a deep look at how China has transformed its capacity for scientific research and innovation provides a window into the country’s ambitions and possible paths in the future.

Samhällsvetenskapen gör samtiden begriplig. Genom att kritiskt granska politik, ekonomi, kommunikation och organisation ger den djupare förståelse för det moderna samhällets förtjänster och problem. Dock bara om den utförs väl, och på allvar tillåts skärskåda gängse föreställningar och företeelser. Under fem övergripande rubriker: Kritisk, Kvalitativ, Konsekvensneutral, Krävande och Konstruktiv, v

The political underperformance, socio-economic grievances, widespread poverty and expansion of terrorist networks in the Sahel region are commonly framed as security risks to both the region itself and to Europe. The heavy international security presence in the region, including a UN peacekeeping mission with a robust mandate, a US Africa Command drone base, three EU missions, a large French-led c

Since the attacks the 11th of September 2001 in the US, there has been a strong increase in security force assistance (SFA) to fragile states with the aim of professionalising security forces, preventing violent extremist organisations (VEO) from exploiting state fragility and, in cases where this has not succeeded, of fighting the latter. At the same time, a shift has taken place with regard to t

African governments have been faster than most of their European counterparts in imposing measures to deal with the COVID-19 outbreak despite dealing with numerous other challenges. However, context matters, and for Africa, the political and socioeconomic consequences of the lockdown measures may cause more havoc than the actual virus.This brief identifies political, economic and social risks rela

How realistic and how fair are the expectations that we place on the small minority of female peacekeepers to bring an ‘added value’ to peace operations? Not at all, I argue in this brief, which examines the instrumentalisation of female participation and suggests that it is time to move beyond the question of an ‘added value’ that often translates into ‘added burden’.Both male and female peacekee

The Corona pandemic is changing the way we live and function as a society for at least the coming weeks or months. While it is a virus that does not take into account race, sex, class or age, it is also quite brutally revealing and reinforcing socio-economic inequalities which reflect the distribution of power in our societies. This, at the same time as it is showing us the strength of empathy, re

Producing original knowledge is the foundation of scientific progress. Originality is associated with certain skills and practices that can be trained and socialised. This study investigates how inbreeding as a career practice influences the socialisation of originality. An analysis based on a sample of mid-career life scientists in Japan finds that originality and associated practices are transfe

Type 1 diabetes (T1D) is a disease of insulin deficiency that results from autoimmune destruction of pancreatic islet β cells. The exact cause of T1D remains unknown, although asymptomatic islet autoimmunity lasting from weeks to years before diagnosis raises the possibility of intervention before the onset of clinical disease. The number, type, and titer of islet autoantibodies are associated wit

The local electronic structure of the metal-active site and the deexcitation pathways of metalloporphyrins are crucial for numerous applications but difficult to access by commonly employed techniques. Here, we applied near-edge X-ray absorption mass spectrometry and quantum-mechanical restricted active space calculations to investigate the electronic structure of the metal-active site of the isol

Optical many-body systems naturally possess strong light-matter interactions and are thus of central importance for photonic applications. However, these applications are so far limited within the regime of intrinsic dynamically stable phases, and the possibility of unstable phases remains unidentified. Here we experimentally revealed a new dynamical phase of intrinsic optical instability by using

Background: Mechanical ventilation is a potentially painful and discomforting intervention that is widely used in neonatal intensive care. Newborn infants demonstrate increased sensitivity to pain, which may affect clinical and neurodevelopmental outcomes. The use of drugs that reduce pain might be important in improving survival and neurodevelopmental outcomes. Objectives: To determine the benefi

Radioactive iodine is commonly used for the treatment of different thyroid conditions since the 1940s. The EANM has developed a standard pre-therapeutic procedure to estimate patient specific thyroid uptake at treatment of benign thyroid diseases. The procedure which models the time dependent fractional thyroid uptake is based on a two-compartment fitting system, one representing the thyroid and t