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n-type Mg3Sb1.5Bi0.5 has recently been discovered to be a promising thermoelectric material, yet the effective n-type dopants are mainly limited to the chalcogens. This may be attributed to the limited chemical insight into the effects from different n-type dopants. By comparing the effects of different chalcogen dopants Q (Q = S, Se, and Te) on thermoelectric properties, it is found that the chal
An experimental campaign has been carried out with the aim of providing an insight into the fracture processes occurring during the cutting of different types of polymers, with features ranging from typically brittle to soft hyperelastic behaviour. The steady state of cutting is investigated using a sharp thin blade, and tracking the insertion force versus the penetration displacement. For soft, h
This study documents how the pore structure develops with time in cement-based materials with varying fly ash replacement. Heat production was measured during the first days, water vapour desorption isotherms were determined at different times up to 18 months, and moisture transport properties were measured after one year. Long-term fly ash reactions alter the pore structure considerably. The fly
The accurate identification of non-metallic inclusions (NMIs) within steel matrices is critical for high-quality steel production. This study employs synchrotron radiation-based X-ray absorption photoemission electron microscopy (X-PEEM) to investigate NMIs in ultra-high-strength steels. Ca-L2,3-edge X-ray absorption spectra were acquired for six NMIs at both room temperature and 400 °C, allowing
Objective: To evaluate the long-term performance of the patch materials we have used to augment the pulmonary arterial tree across a wide spectrum of diagnoses and anatomical locations. Methods: Retrospective, single-center review of 217 consecutive pediatric patients at a tertiary referral center from 1993 to 2020 who underwent patch arterioplasty of the pulmonary arterial tree from the pulmonary
Food wastage during distribution, retail sale, and consumption is a concern of great worry. It not only affects the economics of businesses but also puts natural resources under severe stress. For example, in the UK some 800,000 tons of bakery products are purchased each year and never eaten, mainly due to short life span of the product. Earlier investigations at Lantmännen Unibake, UK have identi
The packaging market is starting to demand renewable materials to face out the fossil based materials mainly used today. This thesis investigate the possibility and advance to switch from conventional grades of polyethylene (PE) and polyethylene terephthalates (PET) towards bio-produced qualities of the same polymers. The work is divided into two parts starting with a carbon dioxide evaluation of
Bio-based materials are considered to be an effective alternative to fossil-based materials and are being studied globally. It will be a long journey for the commercialisation of bio-based materials. Apart from waiting for the material technology to be mature, how will the material be rolled out to the market? This is the challenge faced by all material companies. The project is in collaboration
Cross-laminated timber (CLT) is an engineered wood product constructed by combining multiple layers of wood lamellae with adhesives. In the serviceability state, structural timber elements, that are light–weight, are more susceptible to complications regarding the vibration level, than heavier structural elements such as concrete. Contemporary standard practice in the building industry, is to use
Materials with heterogeneous microstructures have been reported to have an attractive combination of strength and ductility. This is attributed to synergistic strengthening effects from the difference in strength of fine- and coarse-grained regions. Understanding the interaction of the regions is crucial for further optimization of the microstructures. In this work, we fabricated nickel of harmoni
Molybdenum clusters, characterized by their unique structure and intriguing catalytic properties, have gained significant attention in recent years. In several existing studies, density functional theory (DFT) methods have been used to find the lowest energy Mo clusters and explore their electronic and magnetic structure. In all cases, with the exception of a single recent study, where a genetic a
The transition quadrupole moments. Q(t), of four weakly populated collective bands up to spin similar to 65h in Er-157,Er-158 have been measured to be similar to II eb demonstrating that these sequences are associated with large deformations. However, the data are inconsistent with calculated values from cranked Nilsson-Strutinsky calculations that predict the lowest energy triaxial shape to be as
Measurements of top quark spin observables in tt¯ events are presented based on 20.2 fb−1 of s=8 TeV proton-proton collisions recorded with the ATLAS detector at the LHC. The analysis is performed in the dilepton final state, characterised by the presence of two isolated leptons (electrons or muons). There are 15 observables, each sensitive to a different coefficient of the spin density matrix of
Previously proposed high spin states in Na22,23 are compared with calculations from the cranked Nilsson model including Strutinsky renormalization. High K rotational isomers are proposed for Iπ=6- in Na22 and 11/2+, 13/2+, and possibly 15/2+ in Na23. The positive parity yrast sequences in these two nuclei are analyzed in terms of the change from collective to single particle behavior at I=9 (22Na)
