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The active site of the [FeFe] hydrogenases contains two Fe ions bound to one Cys ligand, three CO molecules, two CN(-) ions, and a dithiolate ligand. The nature of the last of these has been much discussed, and it has been suggested that it contains C, N, or O as the bridgehead atom. Most experimental studies indicate a N atom, whereas a recent density functional theory (DFT) study of a crystal st

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Adolescent health is regarded as central to global health goals. Investments made in adolescent health and health services protect the improvements witnessed in child health. Though Saudi Arabia has a large adolescent population, adolescent health-care only began to emerge in recent years, yet widespread uptake has been very limited. Health-care providers are key in addressing and providing the ne

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Asteroseismology has the capability of precisely determining stellar properties that would otherwise be inaccessible, such as radii, masses, and thus ages of stars. When coupling this information with classical determinations of stellar parameters, such as metallicities, effective temperatures, and angular diameters, powerful new diagnostics for Galactic studies can be obtained. The ongoing Stromg

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We have performed the first measurement of the coherent psi(2S) photo-production cross section in ultraperipheral Pb-Pb collisions at the LHC. This charmonium excited state is reconstructed via the psi(2S) -> l(+)l(-) and ->(2S) -> J/psi pi(+)pi(-) decays, where the J/psi decays into two leptons. The analysis is based on an event sample corresponding to an integrated luminosity of about 22 mu b(-1

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Purpose of this paper The purpose of this paper is to examine how logistics performance is affected by the use of different identification technologies and practices for utilising the tracking data. Design/methodology/approach The paper uses the survey method. The survey instrument was developed in co-operation with an expert group consisting of both researchers and industry representatives. The

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Objective. Gastrointestinal (GI) symptoms are common in cirrhosis and have an impact on quality of life. Their pathophysiology and their relation to energy intake have not been fully elucidated and the effect of liver transplantation on GI symptoms has not been studied. We aimed to prospectively evaluate GI symptoms and their determinants before and after transplantation and their potential relati

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Soils are extremely rich in biodiversity, and soil organisms play pivotal roles in supporting terrestrial life, but the role that individual plants and plant communities play in influencing the diversity and functioning of soil food webs remains highly debated. Plants, as primary producers and providers of resources to the soil food web, are of vital importance for the composition, structure, and

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This article presents a specific example of how the work of an editor of the comprehensive historical Swedish dictionary, published by the Swedish Academy, (SAOB) proceeds. The example concerns the Swedish preposition under ’under’ and accurately describes the process of writing that SAOB entry. Drawing from this particular word, it is shown how etymology governs also the semantic description, on

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By means of synchrotron-radiation-based core-level spectroscopies we demonstrate that the degree of corrugation in graphene nanomesh on lattice-mismatched transition-metal substrates critically depends on the strength of chemical bonding at the interface. The degree of interfacial orbital hybridization between graphene and metal states is rising in the series Pt(111)-Ir(111)-Rh(111)-Ru(0001). This

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Teaching the topic of structural dynamics in any engineering field is a true challenge due to the wide span of the underlying subjects like mathematics, mechanics (both rigid-body and continuum mechanics), numerical analysis, random data analysis and physical understanding. In this article we present a pedagogical example of using experimental modal analysis to verify and calibrate a finite-elemen

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Background: Sunitinib malate is approved multinationally for the treatment of metastatic renal cell carcinoma (mRCC) and advanced imatinib-refractory gastrointestinal stromal tumour (GIST). Greater exposure to sunitinib is associated with improved efficacy. Therefore, minimising the impact of adverse events (AEs) on patient quality of life is important to enable patients to achieve optimal exposur

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Introducing a new cat to a home with resident cats may lead to stress, aggression and even fights. In this case study 468 agonistic cat vocalisations were recorded as one cat was introduced to three resident cats in her new home. Six vocalisation types were identified: growl, howl, howl-growl, hiss, spit and snarl. Numerous other intermediate and complex vocalisations were also observed. An acoust

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Despite increasing recognition of the relevance of biological cycling for Si cycling in ecosystems and for Si export from soils to fluvial systems, effects of human cultivation on the Si cycle are still relatively understudied. Here we examined stable Si isotope (delta Si-30) signatures in soil water samples across a temperate land use gradient. We show that - independent of geological and climato

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This letter reports on a search for hypothetical heavy neutrinos, N, and right-handed gauge bosons, W-R, in events with high transverse momentum objects which include two reconstructed leptons and at least one hadronic jet. The results were obtained from data corresponding to an integrated luminosity of 2.1 fb(-1) collected in proton-proton collisions at root s = 7 TeV with the ATLAS detector at t

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Aims and objectives. To describe possible social, nutritional and biological factors influencing iron intake and iron status among healthy one-year-old children in southern Sweden. Background. Iron deficiency is one of the most important nutritional disorders and increases the risk of delayed mental and motor development. Children are at risk because of rapid growth, which entails relatively high

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Purpose: Genome-wide association studies (GWAS) have identified 6q25, which incorporates the oestrogen receptor alpha gene (ESR1), as a quantitative trait locus for areal bone mineral density (BMDa) of the hip and lumbar spine. The aim of this study was to determine the influence of this locus on other bone health outcomes; calcaneal ultrasound (QUS) parameters, radial peripheral quantitative comp