Nonequilibrium Particle Morphology Development in Seeded Emulsion Polymerization. II. Influence of Seed Polymer Tg.
Most structured latex particles are formed in the nonequilibrium state as a result of the reaction kinetics proceeding faster than the phase separation kinetics. Of the many factors controlling such morphologies, the polarity and glass transition temperature (Tg) of the seed polymer are important. In order to study the direct effect of the seed polymer Tg on morphology, we produced a series of pol