Determination of the percolation properties and pore connectivity for mesoporous solids using NMR cryodiffusometry
Using a model disordered mesoporous solid with a spatial arrangement of pore sizes analogous to a macroscopic 'ink-bottle', it has been shown that the hysteresis observed in NMR cryoporometry can be deconvoluted into separate single pore and pore-blocking contributions. The suggestion of pore-blocking effects has been confirmed using PFG NMR. Hence, percolation theory has been used, for the first