On the influence of dielectric saturation and medium granularity on ion-ion interaction and reorganization energies associated with electron-transfer processes in condensed matter
The influence of dielectric saturation effects and the granularity of a medium on the effective ion-ion interaction and the reorganization energy for electron-transfer processes have been studied using a medium built from dipoles and polarizabilities that are placed on a lattice. It was found that these effects lead to an increased repulsion between equally charged ions and an increased attraction