New product from old reaction: uniform magnetite nanoparticles from iron-mediated synthesis of alkali iodides and their protection from leaching in acidic media
Iron-mediated synthesis of alkali metal iodides was quite unexpectedly demonstrated to be able to serve as a cost-efficient and reliable source of spherical single crystalline near-stoichiometric magnetite (Fe3O4) nanoparticles as revealed by TEM and XRD studies and also by XANES spectroscopic quantification of the Fe2+-content. Using the particles as nuclei for the Stoeber synthesis of silica nan